Crowdsourcing of Sensor Cloud Services

The venerable Minisci reaction allows for direct access to functionalized heterocycles. This process has lately seen an interesting renaissance and is discussed in this volume. Addition of heteroatom-centered radicals onto unsaturated systems constitutes another powerful method to construct heterocycles. Examples of such a strategy are proposed along with the formation of various heterocycles relying on homolytic substitution at sulfur, phosphorus and selenium. Additionally free-radical functionalization of reactive functional groups including isonitriles, isothiocyanates and related unsaturated systems which offer a straightforward route towards useful aromatic and non-aromatic heterocycles are discussed.

It brings together a global network of experimentalists, field scientists, theoreticians, chemists, physicists and environmental scientists working at the forefront of these emerging issues, providing a forum for cross-disciplinary exchange and discussion of ideas on the processes that control the composition of the atmosphere.

The current state-of-the-art of green solvents is evaluated along these lines, in addition to reviewing their applications with an appreciation of sustainability criteria. Providing a critical assessment on emerging solvents and featuring case studies and perspectives from different sectors, this is an important reference for academics and industrialists working with solvents, as well as policy-makers involved in bio-based initiatives.